Selective hydrosilylation of N-allylimines using a (3-iminophosphine)palladium precatalyst

Tafazolian Hosein; Schmidt Joseph A. R.

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Selective hydrosilylation of N-allylimines using a (3-iminophosphine)palladium precatalyst

机译：选择性氢化硅烷化N-allylimines使用

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摘要

Hydrosilylation utilizing a (3-iminophosphine)palladium catalyst leads to the selective reduction of the imine unit of allylimines. Successful reduction of twenty-five different substituted aromatic and alkyl allylimines demonstrated the scope and selectivity of this catalytic system.

机译：氢化硅烷化利用(3-iminophosphine)导致了钯催化剂选择性还原亚胺的单位allylimines。不同的取代芳香和烷基allylimines证明了范围和选择性的催化体系。

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来源
《Catalysis science & technology》 |2016年第3期|685-689|共5页
作者
Tafazolian Hosein; Schmidt Joseph A. R.;
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作者单位

Univ Toledo, Coll Nat Sci & Math, Sch Green Chem & Engn, Dept Chem & Biochem, 2801 W Bancroft St,MS 602, Toledo, OH 43606 USA;

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原文格式 PDF
正文语种英语
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关键词
hydrosilylation; imines;

机译：氢化硅烷化;亚胺;

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Selective hydrosilylation of N-allylimines using a (3-iminophosphine)palladium precatalyst

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