Photocatalytic production of hydrogen peroxide from water and dioxygen using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts

Isaka Yusuke; Oyama Kohei; Yamada YusukeSuenobu TomoyoshiFukuzumi Shunichi

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Photocatalytic production of hydrogen peroxide from water and dioxygen using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts

机译：光催化过氧化氢的生产从水和使用cyano-bridged分子氧多核过渡金属配合物作为水氧化催化剂

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Hydrogen peroxide was produced efficiently from water and dioxygen using [Ru-II(Me(2)phen)(3)](2+) (Me(2)phen = 4,7-dimethyl-1,10-phenanthroline) as a photocatalyst and cyano-bridged polynuclear transition metal complexes composed of Fe and Co as water oxidation catalysts in the presence of Sc3+ in water under visible light irradiation.

机译：过氧化氢是有效的水和分子氧使用(2)苯酚的[Ru-II(我)(3)](2 +)(我(2)苯酚的=4 7-dimethyl-1 10-phenanthroline)光催化剂和cyano-bridged多核过渡金属配合物组成的铁和有限公司水氧化催化剂的存在Sc3 +可见光照射下在水中。

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来源
《Catalysis science & technology》 |2016年第3期|681-684|共4页
作者
Isaka Yusuke; Oyama Kohei; Yamada YusukeSuenobu TomoyoshiFukuzumi Shunichi;
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作者单位

Osaka Univ, ALCA, Grad Sch Engn, Dept Mat & Life Sci, Suita, Osaka 5650871, Japan;

Osaka City Univ, Grad Sch Engn, Dept Appl Chem & Bioengn, Osaka 5580022, Japan;

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正文语种英语
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关键词
Oxidation catalysts; oxygen; hydrogen peroxidehydrogen productionPeroxidesDioxygenTransition metal complexes;

机译：氧化催化剂;氧气;氢peroxidehydrogenproductionPeroxidesDioxygenTransition金属复合物;

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Photocatalytic production of hydrogen peroxide from water and dioxygen using cyano-bridged polynuclear transition metal complexes as water oxidation catalysts

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