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Organoselenium-catalyzed selectivity-switchable oxidation of beta-ionone

机译:Organoselenium-catalyzed selectivity-switchablebeta-ionone氧化

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摘要

Catalyzed by organoselenium compounds, beta-ionone was easily oxidized by H2O2 under mild and clean conditions. We were very surprised to find that the reaction selectivity was switchable by the catalyst. To the best of our knowledge, this should be the first example for selectivity regulation using organoselenium catalysts in the field, indicating the great potential of organoselenium catalysis in synthetic organic chemistry in the future.
机译:硒有机化合物催化,beta-ionone是容易被过氧化氢氧化在温和清洁条件。反应的选择性可切换的了催化剂。应该选择性的第一个例子吗监管使用硒有机催化剂字段,显示的巨大潜力硒有机催化在有机合成化学在未来。

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