Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

Hunns James A.; Arroyo Marta; Lee Adam F.Escola Jose M.Serrano DavidWilson Karen

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Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

机译：分级介孔Pd / ZSM-5选择性催化hydrodeoxygenation间甲酚甲基环己烷

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Mesopore incorporation into ZSM-5 enhances the dispersion of Pd nanoparticles throughout the hierarchical framework, significantly accelerating m-cresol conversion relative to a conventional microporous ZSM-5, and dramatically increasing selectivity towards the desired methylcyclohexane deoxygenated product. Increasing the acid site density further promotes m-cresol conversion and methylcyclohexane selectivity through efficient dehydration of the intermediate methylcyclohexanol.

机译：中孔并入ZSM-5增强了钯纳米颗粒的分散层次框架,大大相对于加速间甲酚转换传统的微孔ZSM-5和显著增加对所需的选择性甲基环己烷缺氧的产品。增加酸站点密度进一步推广间甲酚转换和甲基环己烷通过高效的脱水的选择性中间甲基环己醇。

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《Catalysis science & technology》 |2016年第8期|2560-2564|共5页
作者
Hunns James A.; Arroyo Marta; Lee Adam F.Escola Jose M.Serrano DavidWilson Karen;
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作者单位

Rey Juan Carlos Univ, Chem & Environm Engn Grp, Madrid 28933, Spain;

Aston Univ, European Bioenergy Res Inst, Birmingham B4 7ET, W Midlands, England;

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正文语种英语
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关键词
Hierarchical; methylcyclohexane; hydrodeoxygenationMetacresol;

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2. Titanium-Containing Mesoporous Materials: Synthesis and Application in Selective Catalytic Oxidation [J] . Jie Li, Chunhui Zhou, Huali Xie, 天然气化学（英文版） . 2006,第003期
3. Kinetics of selective catalytic reduction of NO by NH3 on Fe-Mo/ZSM-5 catalyst [J] . LI Zhe, SHEN Lin-tao, HUANG Wei, 环境科学学报：英文版 . 2007,第012期
4. In-situ　Infrared　Study　on　Surface　Species　in　Selective　Catalytic　Reduction　of　NO　with　Hydrocarbon　over　Copper　ZSM-5　Zeolite [J] . 高等学校化学研究：英文版 . 1997,第002期
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Hierarchical mesoporous Pd/ZSM-5 for the selective catalytic hydrodeoxygenation of m-cresol to methylcyclohexane

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