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首页> 外文期刊>Chemical Engineering Research & Design: Transactions of the Institution of Chemical Engineers >Chromatographic separation of wood model constituents—Mathematical modeling and parameter estimation
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Chromatographic separation of wood model constituents—Mathematical modeling and parameter estimation

机译:色谱分离的木头模型constituents-Mathematical建模和参数估计

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摘要

A mathematical model of the hydrophobic adsorption chromatographic separation of wood model constituents has been developed. Veratryl alcohol was selected to illustrate a lignin molecule and salicin was selected to illustrate a lignin-carbohydrate complex. A variety of available experimental methods in combination with parameter fitting was used to estimate the parameters of packed bed porosity, axial dispersion, film mass transfer, diffusivities and adsorption equilibria with a phenylic silica stationary phase. The model was verified to simulate the separation to within an accuracy of 95%. The model was, however, unable to predict the phenomenon of elution curve fronting, caused by the channeling of the packed bed.
机译:疏水吸附的数学模型色谱分离的木头模型选民了。被选来说明木质素分子水杨苷被选来说明lignin-carbohydrate复杂。可用实验方法的组合与参数拟合被用来估计填充层孔隙度参数,轴向分散,电影质量传递、扩散系数和phenylic二氧化硅吸附平衡固定相。模拟精度内的分离95%。洗脱曲线面对的现象,造成的通灵的填充床。

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