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Photochemical Flow Reactions

机译:光化学反应流

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The versatility of photochemical flow processes is rapidly expanding, and we suggest that this technique is capable of broadening the general appeal and impact of photochemistry similar or even to a greater extent to what microwave technology has done to thermal processes. This review highlights the recent developments that support this suggestion as well as the technological challenges that have yet to be resolved. Continuous photoflow reactions allow for better control over heating and mixing, are safer to operate on scale-up, in particular if LEDs are used in place of Hg lamps, they offer a higher surface/volume ratio and more efficient light penetration than batch mode photoreactions, and furthermore allow for the removal of products in-line to avoid secondary decompositions and poor conversions.
机译:光化学流过程的多功能性迅速扩大,我们建议技术可以扩大的吸引力和影响光化学或相似甚至在更大程度上微波技术做了热过程。概述了最近的发展支持这个建议的还有待技术挑战解决。为了更好的控制加热和搅拌,安全操作扩大,特别是如果发光二极管代替Hg灯使用,他们提供更高的表面/体积比和更有效率光比批处理模式渗透光化反应,而且允许删除产品避免二次分解和内联可怜的转换。

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