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Facile preparation of activated carbon with optimal pore range for high butane working capacity

机译:简单的制备活性炭最佳的孔隙范围高丁烷工作能力

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摘要

In this work, the correlation between the pore characteristics of activated carbon (AC) and the adsorption/desorption characteristics of evaporated fuel was studied. AC was prepared by various physical re-activation methods using coconut-derived commercial AC. Pore characteristics of the re-activated AC were investigated using N-2/77 K adsorption isotherms. The structural characteristics of the AC were observed by X-ray diffraction and Raman spectroscopy. The butane working capacity was observed according to ASTM D5228. From the results, the specific surface area and total pore volume of the ACs were determined to be 1380-2040 m(2)/g and 0.60-0.96 cm(3)/g, respectively. It was also observed that various pore size distributions were found to be dependent on the functions of the activation method and time. A close relationship between butane activity/retentivity and micropore/mesopore volumes was found. In addition, it was inferred that the volume fraction of micropores and sub-mesopores with diameters between 1.5 and 3.0 nm primarily controls butane activity.
机译:在这部作品中,孔隙之间的相关性活性炭(AC)和特征吸附/解吸特征蒸发燃料进行了研究。各种物理再活跃的方法使用coconut-derived商业交流。孔隙重新启动交流的特点调查使用N-2/77 K吸附等温线。交流的结构特点通过x射线衍射和拉曼光谱学。根据ASTM D5228观察。结果,比表面积和总孔ACs的决心是1380 - 2040米(2)/ g和0.60 - -0.96厘米(3)/ g,分别。也观察到,不同孔隙大小分布依赖于被发现激活方法和时间的函数。丁烷之间密切的关系活动/记忆力和微孔、中孔卷被发现。微孔隙的体积分数sub-mesopores直径在1.5和3.0之间纳米丁烷主要控制活动。

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