Determination of the absolute stereochemistry of ( +)?solaniol

Cheka Kehelpannala; G. R. Nalin Rathnayake; Dilhara DissanayakeDinusha KanatiwelaN. Savitri KumarNimal AdikaramLalith JayasingheHiroshi ArayaYoshinori Fujimoto

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Determination of the absolute stereochemistry of ( +)?solaniol

机译：绝对构型的确定(

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The absolute stereochemistry of ( +)-solaniol (5,8-dihydroxy-7-(2-hydroxypropyl)-2-methoxy-6-methyl-1,4-naphthoquinone) (1) was deduced to be S using Mosher’s method. Our result did not accord with the R configuration of ( +)-solaniol recently proposed by Maharjan et al., but agreed with the S configuration determined by X-ray crystallographic analysis by Kyekyeku et al. In addition, complete and unambiguous assignments of 13C NMR signals for 1 are reported.

机译：(+)的绝对立体化学-solaniol(5、8

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来源
《Chemical papers》 |2021年第5期|2233-2235|共3页
作者
Cheka Kehelpannala; G. R. Nalin Rathnayake; Dilhara DissanayakeDinusha KanatiwelaN. Savitri KumarNimal AdikaramLalith JayasingheHiroshi ArayaYoshinori Fujimoto;
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作者单位

National Institute of Fundamental Studies, Hantana Road, Kandy, Sri Lanka;

School of Agriculture, Meiji University, Kawasaki, Kanagawa 214?8571, Japan;

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原文格式 PDF
正文语种英语
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Naphthoquinones; stereochemistry; Sulfuraluminium;

机译：萘醌、立体化学、Sulfuraluminium;

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Determination of the absolute stereochemistry of ( +)?solaniol

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