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A crystalline and 3D periodically ordered mesoporous quaternary semiconductor for photocatalytic hydrogen generation

机译：一个水晶和3 d周期性地命令介孔四元半导体的光催化氢代

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摘要

We have prepared the first crystalline and 3D periodically ordered mesoporous quaternary semiconductor photocatalyst in an evaporation-induced self-assembly assisted soft-templating process. Using lab synthesized triblock-terpolymer poly(isoprene-b-styrene-b-ethylene oxide) (ISO) a highly ordered 3D interconnected alternating gyroid morphology was achieved exhibiting near and long-range order, as evidenced by small angle X-ray scattering (SAXS) and electron microscopy (TEM/SEM). Moreover, we reveal the formation process on the phase-pure construction of the material's pore-walls with its high crystallinity, which proceeds along a highly stable W5+ compound, by both in situ and ex situ analyses, including X-ray powder diffraction (XRPD), Fourier transform infrared spectroscopy (FTIR) and electron paramagnetic resonance (EPR). The resulting photocatalyst CsTaWO6 with its optimum balance between surface area and ordered mesoporosity ultimately shows superior hydrogen evolution rates over its non-ordered reference in photocatalytic hydrogen production. This work will help to advance new self-assembly preparation pathways towards multi-element multifunctional compounds for different applications, including improved battery and sensor electrode materials.
机译：我们准备了第一个水晶和3 d定期有序介孔四元半导体光催化剂的evaporation-induced自组装辅助极富过程。triblock-terpolymer聚(氧化isoprene-b-styrene-b-ethylene) (ISO)高度有序的3 d互连交替gyroid形态学实现展示近了和远程命令,小角度就证明了这一点x射线散射(粉煤灰)和电子显微镜(TEM和SEM)。phase-pure建设的过程材料的pore-walls高沿着高结晶度,收益稳定W5 +复合,通过原位和非原位分析,包括x射线粉末衍射(XRPD),傅里叶变换红外光谱学(红外光谱)和电子顺磁共振(EPR)。由此产生的光催化剂CsTaWO6与它最佳的表面积和命令之间的平衡中孔隙最终显示了优越的氢进化率对其non-ordered参考光催化制氢。将有助于推进新的自组装吗准备向多元化的途径多功能化合物对不同应用程序,包括电池和改善传感器电极材料。

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