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Section 15. Chemistry: SYNTHESIS OF CYCLIC ACETALS OF VINYLOXYCYCLOPROPANES AND PHOTOSENSITIVE POLYMERS ON THEIR BASIS

机译:第15款.化学:乙烯氧基环丙烷环缩醛及其光敏聚合物的合成

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摘要

The synthesis of cyclic acetals of cyclopropane-containing vinyl ethers has been carried out and their homopolymerization and copolymerization with maleic anhydride in the radical conditions have been carried out. The interrelation between copolymerization process and formation of the complexes of donor-acceptor type between comonomers in the system has been studied. By a method ofPMR-spectroscopy the formation of donor-acceptor complexes between comonomers has been revealed. The photosensitivity of the films of the synthesized copolymers has been investigated and it has been shown that it depends on MW, solubility of polymer, nature of functional substituent and a number of other factors.
机译:环缩醛的合成cyclopropane-containing乙烯基醚和他们的均聚和执行与马来酸酐共聚进行了彻底的条件。共聚过程之间的相互关系、亲水的复合物的形成共聚单体之间的系统类型研究。亲水复合物之间的形成共聚单体被发现。合成的光敏性的电影共聚物已经调查它表明,这取决于兆瓦,溶解度聚合物,功能取代基的性质一些其他的因素。

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