Synthesis, Crystal Structure, Fluorescence and Photocatalytic Properties of a Copper Compound with 2-Phenyl-1H-1,3,7,8-tetraazacyclopentaIphenanthrene and Silicotungstic Acid

Xu Dongbo; Luo Bifu; Chen MinMeng SuciWu YunlongJiang Deli

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Synthesis, Crystal Structure, Fluorescence and Photocatalytic Properties of a Copper Compound with 2-Phenyl-1H-1,3,7,8-tetraazacyclopentaIphenanthrene and Silicotungstic Acid

机译：2-苯基-1H-1,3,7,8-四氮杂环戊二烯并I菲和硅钨酸铜化合物的合成、晶体结构、荧光和光催化性能

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The polyoxometalate compound CuPTCP(H2O)(2.5)(2)SiW(12)O40center dot 10.5H(2)O (1) was synthesized under hydrothermal conditions using 2-phenyl-1H-1,3,7,8-tetraazacyclopentalliphenanthrene (PTCP) and Keggin-type silicotungstic acid (H4SiW12O4) as neutral ligands. Compound 1 was characterized by single-crystal X-ray diffraction, elemental analysis, as well as IR and UV/Vis spectroscopy. It crystallizes in the orthorhombic space group Cmcm with a = 15.490(8) nm, h = 25.263(8) nm, c = 20.988(8) a = 90 degrees, beta = 90 degrees, gamma = 90 degrees, V = 8213(6) nm(3), Z = 2. Compared with the ligand PTCR the fluorescent spectra of compound 1 are different. Furthermore, the Rhodamine B (RhB) photodegration process by compound 1 as catalyst was studied. It could be shown that the DR of compound 1 is more than twice that of pure silicotungstic acid.

机译：以2-苯基-1H-1,3,7,8-四氮杂环戊钨酸（H4SiW12O4）为中性配体，在水热条件下合成了多金属氧酸盐化合物[CuPTCP（H2O）（2.5）]（2）[SiW（12）O40]中心点10.5H（2）O（1）。通过单晶X射线衍射、元素分析以及红外和紫外/可见光谱对化合物1进行了表征。它在斜方格空间群 Cmcm 中结晶，a = 15.490（8） nm，h = 25.263（8） nm，c = 20.988（8） a = 90 度，beta = 90 度，gamma = 90 度，V = 8213（6） nm（3），Z = 2。与配体PTCR相比，化合物1的荧光光谱不同。此外，还研究了以化合物1为催化剂的罗丹明B（RhB）光脱化工艺。可以看出，化合物1的DR%是纯硅钨酸的两倍以上。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2015年第5期|826-830|共5页
作者
Xu Dongbo; Luo Bifu; Chen MinMeng SuciWu YunlongJiang Deli;
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作者单位

Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China;

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正文语种英语
中图分类化学;
关键词
2-Phenyl-1H-1; 3; 7; 8-tetraazacyclopentaIphenanthrene; Silicotungstic acid; Copper; Fluorescence; Photocafalytic activity;

机译：2-苯基-1H-1;3;7;8-四氮杂环戊二烯并[I]菲;硅钨酸;铜;荧光;光溶活性;

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Synthesis, Crystal Structure, Fluorescence and Photocatalytic Properties of a Copper Compound with 2-Phenyl-1H-1,3,7,8-tetraazacyclopentaIphenanthrene and Silicotungstic Acid

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