Syntheses, Crystal Structures, and Luminescence Properties of Four Coordination Polymers Based on 1,3,5-Tris (imidazol-1-yl)benzene

Liu Xinzheng; Chen Hongtai; Fan LimingZhang Xiutang

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Syntheses, Crystal Structures, and Luminescence Properties of Four Coordination Polymers Based on 1,3,5-Tris (imidazol-1-yl)benzene

机译：基于1,3,5-三（咪唑-1-基）苯的四种配位聚合物的合成、晶体结构及发光性能

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Based on the tripodal 1,3,5-tris(imidazol-1-yl)benzene (tib) ligand, four transition metal coordination polymers, namely, {Ni-3(tib)(2)(H2O)(12)(SO4)(3)}(n) (1), {Co-1/6(tib)(1/3)(O)(1/3)}(n) (2), and M(tib)(hip)(n) (M = Mn for 3, and M = Co for 4) (hip = 5-hydroxyisophthalic acid), were synthesized through solvothermal method. Their structures were defined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses (EA), IR spectra, powder X-ray diffraction (PXRD), and thermogravimetric analyses (TGA). Complex 1 displays a 2D 3-connected (6(3)) hcb net. Complex 2 is a 2D (3,6)-connected (4(3))(2)(4(6).6(6).8(3)) kgm net. Complex 3 and 4 present similar 2D 4-connected (4(4).6(2)) sql net. Moreover, the solid state luminescence properties of complexes 1 and 3 were investigated.

机译：基于三足醛1,3,5-三（咪唑-1-基）苯（tib）配体，采用溶剂热法合成了4种过渡金属配位聚合物，即{[Ni-3（tib）（2）（H2O）（12）]（SO4）（3）}（n）（1）、{[Co-1/6（tib）（1/3）]（O）（1/3）}（n）（2）和[M（tib）（hip）]（n）（M = Mn，M = Co for 4）（hip = 5-羟基间苯二甲酸）。通过单晶X射线衍射分析确定其结构，并通过元素分析（EA）、红外光谱、粉末X射线衍射（PXRD）和热重分析（TGA）进一步表征。复合体 1 显示一个 2D 3 连接的（6（3）） HCB 网络。配合物 2 是 2D （3,6）连接的（4（3））（2）（4（6）.6（6）.8（3）） kgm 网。复数 3 和 4 呈现类似的 2D 4 连接（4（4）.6（2）） sql net。此外，还研究了配合物1和3的固态发光性能。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2017年第2期|192-197|共6页
作者
Liu Xinzheng; Chen Hongtai; Fan LimingZhang Xiutang;
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作者单位

Qilu Normal Univ, Coll Chem & Chem Engn, Adv Mat Inst Res, Jinan 250013, Peoples R China;

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正文语种英语
中图分类化学;
关键词
1; 3; 5-Tris(imidazol-1-yl)benzene; 5-Hydroxyisophthalic acid; Solvothermal methods; Luminescence properties;

机译：1;3;5-三（咪唑-1-基）苯;5-羟基间苯二甲酸;溶剂热法;发光特性;

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Syntheses, Crystal Structures, and Luminescence Properties of Four Coordination Polymers Based on 1,3,5-Tris (imidazol-1-yl)benzene

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