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EPR of Graphite and Fullerenes

机译:石墨和富勒烯的 EPR

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Analysis of the EPR results for graphite and fullerenes has led to the development of a model for theg-factor in follerene based on the analogy between graphite and fullerene. Pressure dependence ofg-factor in C60powder confirms the validity of this model.13C hyperfine splitting ofa0.36 mT in pristine fullerene is also reported. Theg-factors of C60−1and C60−3in a solution and in a different K°C60fullerides are presented. C60+nstates should be described by the spectroscopic splitting factor larger than that of a free spin.
机译:对石墨和富勒烯的EPR结果的分析导致了基于石墨和富勒烯之间的类比的follerene中g因子模型的开发。C60粉末中g因子的压力依赖性证实了该模型的有效性.13C还报道了原始富勒烯中a0.36 mT的超精细分裂。提出了 C60−1 和 C60−3 在溶液和不同 K°C60富勒德斯中的 g 因子。C60+n态应用大于自由自旋的光谱分裂因子来描述。

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