SYNTHESIS AND REACTIONS OF (O-(BIS(DIMETHYLAMINO)BORYLMETHYL)PHENYL)DIPHENYLPHOSPHANE

Braunschweig H.; Englert U.; Dirk R.

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SYNTHESIS AND REACTIONS OF (O-(BIS(DIMETHYLAMINO)BORYLMETHYL)PHENYL)DIPHENYLPHOSPHANE

机译：（O-（双（二甲基氨基）硼基甲基）苯基）二苯基膦的合成与反应

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The new alpha,omega-boryl(organyl)phosphane o-Ph2PC6H4CH2B(NMe2)(2) (10) was obtained in good yields from the reaction of ClB(NMe2)(2) with o-Ph2PC6H4CH2Li(tmeda). Five derivatives of 10 were obtained by substituting the boron-bound amino groups by reactions with MeOH, BCl3, HCl, and LiAlH4, respectively, in particular, o-Ph-2(HCl)PC6H4CH2BCl2(HNMe2) (10e) which shows a unique P-H-Cl-H-N unit. Compound 10 and its derivatives were characterized by multinuclear NMR methods, mass spectra, and elemental analyses. In addition, the structure of 10e . 1.5 C6H6 was determined by single crystal X-ray diffraction. References: 14

机译：ClB（NMe2）（2）与o-Ph2PC6H4CH2Li（tmeda）反应得到新的α，omega-[硼基（有机基）]膦o-Ph2PC6H4CH2B（NMe2）（2）（2）（10）。通过与MeOH、BCl3、HCl和LiAlH4反应取代硼结合氨基，分别得到10的5个衍生物，特别是o-Ph-2（HCl）PC6H4CH2BCl2（HNMe2）（10e），表现出独特的P-H-Cl-H-N单元。通过多核核磁共振方法、质谱和元素分析对化合物10及其衍生物进行了表征。此外，10e的结构。1.5 C6H6采用单晶X射线衍射法测定。[参考资料： 14]

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |1997年第7期|1093-1097|共5页
作者
Braunschweig H.; Englert U.; Dirk R.;
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RHEIN WESTFAL TH AACHEN INST ANORGAN CHEM TEMPLERGRABEN 55 D-52056 AACHEN GERMANY;

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正文语种英语
中图分类化学;
关键词
(borylorganyl)phosphanes; (borylorganyl)phosphoniumsalt; X-ray structure; Phosphorus; Crystal; Bromide;

机译：（硼基有机基）膦;（硼基有机基）膦酸盐;X射线结构;磷;水晶;溴化物;

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1. ChemInform Abstract: Synthesis of Novel Divalent Organotin Compounds Containing the Chiral C,N(2‐(Dimethylamino)phenyl)(trimethylsilyl)methyl or 2‐(1‐(Dimethylamino)ethyl)phenyl Chelating Ligand. [J] . J. T. B. H. JASTRZEBSKI, P. VAN DER SCHAAF, J. BOERSMAG. VAN KOTEN Chem Inform . 1992,第22期

机译：ChemInform Abstract: Synthesis of Novel Divalent Organotin Compounds Containing the Chiral C,N(2‐(Dimethylamino)phenyl)(trimethylsilyl)methyl or 2‐(1‐(Dimethylamino)ethyl)phenyl Chelating Ligand.
2. Polarized twisted ethylenes: structures of 3‐bis(dimethylamino)methylene‐3‐phenyl‐2‐propanone (I), C14H20N2O, and methyl 2‐bis(dimethylamino)methylene‐3‐oxobutyrate trihydrate (II), C14H18N2O3.3H2O [J] . N. U. Kamath, K. Venkatesan Acta Crystallographica. Sect.C, Section C. Crystal Structure Communications . 1984,第3期

机译：Polarized twisted ethylenes: structures of 3‐bis(dimethylamino)methylene‐3‐phenyl‐2‐propanone (I), C14H20N2O, and methyl 2‐bis(dimethylamino)methylene‐3‐oxobutyrate trihydrate (II), C14H18N2O3.3H2O
3. ChemInform Abstract: Bridging of Platinacycles by cis‐Azobenzenes: Synthesis and Photochemical Study. Structure of the Twisted Inorganic Z‐1,1,2,2‐ Tetrasubstituted Diazaethene ((Z)‐1,2‐Diphenyldiazaethene)bis(chloro((( dimethylamino)methyl)phenyl‐C,N)platinum(II)). [J] . A. D. RYABOV, L. G. KUZMINA, N. V. DVORTSOVAD. J. STUFKENSR. VAN ELDIK Chem Inform . 1993,第44期

机译：ChemInform Abstract: Bridging of Platinacycles by cis‐Azobenzenes: Synthesis and Photochemical Study. Structure of the Twisted Inorganic Z‐1,1,2,2‐ Tetrasubstituted Diazaethene ((Z)‐1,2‐Diphenyldiazaethene)bis(chloro((( dimethylamino)methyl)phenyl‐C,N)platinum(II)).
4. Synthesis of Heteronuclear Bidentate Lewis Acids, o-(Boryl)(fIuorosiryl)benzenes, and Their Complexation Behaviors with Fluoride Ion [C] . Atsushi Kawachi, Atsushi Tani, Junper Shimada Symposium on Organometallic Chemistry . 2007

机译：合成异核双齿路易斯酸，O-（Boryl）（FiOorosirylyl）苯并，及其氟离子的络合行为
5. 14-Phenylenebis(methylene)bis(triphenylphosphonium) bis(tetrafluoroborate) [O] . Hamisu Ibrahim, Neil Koorbanally, Deresh Ramjugernath, 2011

机译：14-Phenylenebis(methylene)bis(triphenylphosphonium) bis(tetrafluoroborate)
6. [1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate) [O] . Ibrahim, Hamisu, Koorbanally, Neil, Ramjugernath, Deresh, 2011

机译：[1,4-Phenylenebis(methylene)]bis(triphenylphosphonium) bis(tetrafluoroborate)

SYNTHESIS AND REACTIONS OF (O-(BIS(DIMETHYLAMINO)BORYLMETHYL)PHENYL)DIPHENYLPHOSPHANE

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