Chiral (Pyridine)-(Imidazoline) NCN? Pincer Palladium(II) Complexes: Convenient Synthesis via C-H Activation and Characterization

Wang Yi-Dong; Liu Jin-Kui; Yang Xue-JieGong Jun-FangSong Mao-Ping

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Chiral (Pyridine)-(Imidazoline) NCN? Pincer Palladium(II) Complexes: Convenient Synthesis via C-H Activation and Characterization

机译：Chiral (Pyridine)-(Imidazoline) NCN? Pincer Palladium(II) Complexes: Convenient Synthesis via C-H Activation and Characterization

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A series of aryl-based chiral NCN ' pincer palladium(II) complexes 4a-k were synthesized via C-H activation of the (pyridyl)-(imidazolinyl)benzene ligands, which proceeded smoothly with PdCl2 as the palladium source in the presence of Et3N or NaHCO3 base in toluene under reflux. All of the complexes have been characterized by elemental analysis and H-1 and C-13{H-1} NMR spectroscopy. In addition, the molecular structures of complexes 4a, 4c, and 4f have been determined by X-ray single-crystal diffraction analysis. The obtained chiral Pd pincers were applied to catalytic asymmetric reactions of acrylonitrile and dichloroacetonitrile with sulfonimines. With a catalyst loading of 5 mol % and the assistance of AgOAc, these complexes acted as active but moderately stereoselective catalysts for the aforementioned reactions.

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来源
《Organometallics》 |2022年第8期|984-996|共13页
作者
Wang Yi-Dong; Liu Jin-Kui; Yang Xue-JieGong Jun-FangSong Mao-Ping;
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Zhengzhou Univ;

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正文语种英语
中图分类元素有机化合物;
关键词
CATALYTIC ENANTIOSELECTIVE REACTION; MANNICH-TYPE REACTION; CRYSTAL-STRUCTURES; NICKEL(II) COMPLEXES; LIGANDS SYNTHESIS; ASYMMETRIC ALDOL; HIGHLY EFFICIENT; IMINES; BEARING; PD(II);

Chiral (Pyridine)-(Imidazoline) NCN? Pincer Palladium(II) Complexes: Convenient Synthesis via C-H Activation and Characterization

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