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Seasonal variations in the major chemical species of snow at the South East Dome in Greenland

机译：Seasonal variations in the major chemical species of snow at the South East Dome in Greenland

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We analyze snow-pit samples collected in May 2015 at the South East Dome (SE Dome) on the Greenland ice sheet. The analysis includes high-resolution records of delta D and delta O-18, as well as the major ions, CH3SO3-, Cl-, NO3-, SO42-, Na+, NH4+, K+, Ma(2+), and Ca2+. We find that the 3.55-m snow pit recorded temperature and aerosol proxies back to summer or autumn of 2014. This indicates a higher accumulation rate than those at other major drilling sites in Greenland. Due to this high accumulation rate, ion concentrations except Na+ are lower than those typical of the central Greenland ice sheet. Concerning seasonal variability, the Na+, Cl-, Ca2+, Mg2+, and NO3- vary similarly to other sites in Greenland, with the Na+ and Cl- peaking in winter to early spring, Ca2+ peaking in spring, Mg2+ peaking in winter to spring, and NO3- towards a peak in summer while showing smaller peaks in winter to spring. The NH4+ increased in spring, and SO42- increased in autumn to winter at SE Dome. On the other hand, the seasonal trend in the Cl-/Na+ ratio differs from those in the inland region. As we did not fully recover one seasonal cycle, some seasonal peaks may have been missed. (C) 2016 Elsevier B.V. and NIPR. All rights reserved.

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