NH_4BAsO_4F - A new layer fluoro-boroarsenate with a silicate related topology

Lieb A.; Weller M.T.

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NH_4BAsO_4F - A new layer fluoro-boroarsenate with a silicate related topology

机译：NH_4BAsO_4F - 具有硅酸盐相关拓扑结构的新层氟硼砷酸盐

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The fluoro-boroarsenate NH_4BAsO_4F has been obtained by the melt reaction of NH_4H_2 AsO_4, B(OH) _3 and LiBF_4. The dry reaction mixture, in a 3:3:2 ratio, was treated at 240°C for 14 days. After cooling to room, temperature and washing with hot water, the product was isolated as colourless crystals and powder. The crystal, structure was determined by single-crystal X-ray diffraction. The structure consists of BASO_4F~- layers, separated by ammonium ions, having a unique orientation pattern of the tetrahedra forming the constituent sixmembered rings. The topology of the fluoro-boroarsenate layer is related to those of the silicate δ-Na _2Si_2O_5 and the borophosphate Mg(H _2O)_2B_2P_2O_8(OH) _2·H_2O. NH_4BAsO_4F was further characterised by powder X-ray diffraction, IR spectroscopy and EDX analyses.

机译：氟硼砷酸酯NH_4[BAsO_4F]由NH_4H_2 AsO_4、B（OH）_3和LiBF_4熔融反应得到。将干反应混合物以3：3：2的比例在240°C下处理14天。冷却至室温，用热水洗涤后，分离出产品，为无色结晶和粉末。晶体结构通过单晶X射线衍射确定。该结构由[BASO_4F]~-层组成，由铵离子隔开，具有形成组成六元环的四面体的独特取向模式。氟硼砷酸盐层的拓扑结构与硅酸盐δ-Na _2Si_2O_5和磷酸硼酸盐Mg（H _2O）_2[B_2P_2O_8（OH） _2]·H_2O. NH_4[BAsO_4F]通过粉末X射线衍射、红外光谱和EDX分析进一步表征了这些表征。

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《Zeitschrift fur Anorganische und Allgemeine Chemie》 |2009年第12期|1877-1881|共5页
作者
Lieb A.; Weller M.T.;
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作者单位

School of Chemistry, University of Southampton, University Road, Southampton SO17 1BJ, United Kingdom;

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原文格式 PDF
正文语种英语
中图分类化学;
关键词
Ammonium; Arsenate; Boron; Phosphate; Silicate; X-ray diffraction;

机译：铵;砷酸盐;硼;磷酸盐;硅酸盐;X射线衍射;

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1. NH_4[BAsO_4F] - A new layer fluoro-boroarsenate with a silicate related topology [J] . Lieb A., Weller M.T. Zeitschrift fur Anorganische und Allgemeine Chemie . 2009,第12期

机译：NH_4 [BAsO_4F]-具有硅酸盐相关拓扑结构的新层氟硼砷酸盐
2. Data on Mineral Research Described by Researchers at Moscow MV Lomonosov State University (Rb1.66cs1.34tbSi5.43ge0.57o15Center Dot H2o, a New Member of the Od-family of Natural and Synthetic Layered Silicates: Topology-symmetry Analysis and ...) [J] . Mining & Minerals . 2021,第18期

机译：Data on Mineral Research Described by Researchers at Moscow MV Lomonosov State University (Rb1.66cs1.34tbSi5.43ge0.57o15Center Dot H2o, a New Member of the Od-family of Natural and Synthetic Layered Silicates: Topology-symmetry Analysis and ...)
3. Synthesis and Crystal Structure of a Layered Silicate HUS-1 with a Halved Sodalite-Cage Topology [J] . Ikeda Takuji, Oumi Yasunori, Honda KoutaroSano TsunejiMomma KoichiIzumi Fujio Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2011,第6期

机译：Synthesis and Crystal Structure of a Layered Silicate HUS-1 with a Halved Sodalite-Cage Topology
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NH_4BAsO_4F - A new layer fluoro-boroarsenate with a silicate related topology

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