Simple Electrochemical Characterization of ortho-carborane and Some of its Exo-skeletal Derivatives

Fojt Lukas; Nekvinda Jan; El Anwar SuzanGruner BohumirHavran LudekFojta Miroslav

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Simple Electrochemical Characterization of ortho-carborane and Some of its Exo-skeletal Derivatives

机译：Simple Electrochemical Characterization of ortho-carborane and Some of its Exo-skeletal Derivatives

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Electrochemical behaviour of 12 icosahedral carboranes - ortho-, meta- and para-carborane with different exo-skeletal substituents was investigated. The study was done using phosphate buffers, in some cases with 20 % and 30 % dimethyl sulfoxide (DMSO) addition to increase the solubility of studied compounds. Commercial glassy carbon electrode or home-made screen printed electrodes were used. Distinct electrochemical responses were observed only for the ortho-carborane and its exo-skeletal derivatives. The study of different exo-skeletal substituents on the electrochemical behaviour of the carboranes is crucial for the intended use of these compounds as electrochemical labels of biomolecules.

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来源
《Electroanalysis》 |2020年第8期|1859-1866|共8页
作者
Fojt Lukas; Nekvinda Jan; El Anwar SuzanGruner BohumirHavran LudekFojta Miroslav;
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作者单位

Czech Acad Sci, Inst Biophys, Kralovopolska 135, Brno 61265, Czech Republic;

Czech Acad Sci, Inst Inorgan Chem, Hlavni 1001, Rez 25068, Czech Republic;

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正文语种英语
中图分类电化学、电解、磁化学;
关键词
electrochemistry; carboranes; molecular sensors and probes; screen printed electrodes; glassy carbon electrode;

Simple Electrochemical Characterization of ortho-carborane and Some of its Exo-skeletal Derivatives

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