SYNTHESIS OF THE DIRHENIUM(III) CLUSTER COMPOUND WITH CYSTEINE

A.A.Golichenko; A.A.Ovcharenko; N.I.ShtemenkoA.V.Shtemenko

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SYNTHESIS OF THE DIRHENIUM(III) CLUSTER COMPOUND WITH CYSTEINE

机译：SYNTHESIS OF THE DIRHENIUM(III) CLUSTER COMPOUND WITH CYSTEINE

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Synthesis of the dirhenium(III) cluster compound with cysteine was elaborated. Composition and structure of the obtained dichlorotetra-μ-cysteinatodirhenium(III) chloride with formula [Re_2(Cys)_4Cl_2]Cl_4 (1) was confirmed by molar electric conductivity, elemental analysis, infrared-, mass- and electronic spectroscopy. Thermal behavior of 1 was investigated that confirmed the structure of 1. Conversion of the coordinated cysteine to cystine in the inner sphere of 1 was detected during its mass spectral decomposition.

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《Украинский химический журнал: Ежемес. науч. журн.》 |2016年第8期|34-39|共6页
作者
A.A.Golichenko; A.A.Ovcharenko; N.I.ShtemenkoA.V.Shtemenko;
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作者单位

Ukrainian State University of Chemical Technology, 8 Gagarin Avenue, Dnipro, 49005, Ukraine;

Palladin Institute of Biochemistry, National Academy of Sciences of Ukraine, 9 Leontovich Str., Kiev, 01601, Ukraine;

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收录信息美国《科学引文索引》(SCI);
原文格式 PDF
正文语种英语
中图分类化学;
关键词
dirhenium (III); quadruple bond; cysteine; infrared-; mass-; electronic spectroscopy;

SYNTHESIS OF THE DIRHENIUM(III) CLUSTER COMPOUND WITH CYSTEINE

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