Electrocatalytic Kinetics of N-Hydroxynaphthalimide as a Redox Mediator for Benzyl Alcohol Oxidation Using Rotating Disk Electrode Voltammetry

kishioka Shinya

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Electrocatalytic Kinetics of N-Hydroxynaphthalimide as a Redox Mediator for Benzyl Alcohol Oxidation Using Rotating Disk Electrode Voltammetry

机译：Electrocatalytic Kinetics of N-Hydroxynaphthalimide as a Redox Mediator for Benzyl Alcohol Oxidation Using Rotating Disk Electrode Voltammetry

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Abstract Electrode reaction and electrocatalytic kinetics of N-hydroxynaphthaleneimide (NHNI) as a redox mediator for benzyl alcohol oxidation in acetonitrile were examined by cyclic voltammetry and rotating disk electrode voltammetry. Cyclic voltammograms of NHNI in acetonitrile showed an increase in chemical reversibility with the addition of lutidine as a base, as the irreversible oxidation peak shifted to a negative potential and a reduction peak appeared. Coexistence of benzyl alcohol in addition to the base increased the oxidation current, confirming the catalytic reaction. The quantitative analysis of the electrocatalytic reaction was conducted, and the second-order rate constant for the oxidation of benzyl alcohol was estimated.Graphical abstract

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来源
《Electrocatalysis》 |2022年第2期|210-217|共8页
作者
kishioka Shinya;
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作者单位

Gunma University;

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原文格式 PDF
正文语种英语
中图分类化学动力学、催化作用;
关键词
N-Hydroxynaphthaleneimide; Benzyl alcohol; N-oxyl radical; lignin oxidation; Mediator; Rotating disk electrode voltammetry;

Electrocatalytic Kinetics of N-Hydroxynaphthalimide as a Redox Mediator for Benzyl Alcohol Oxidation Using Rotating Disk Electrode Voltammetry

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