• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Advanced energy materials >A Novel Plastic-Crystal Electrolyte with Fast Ion-Transport Channels for Solid Zinc-Ion Batteries
【24h】

A Novel Plastic-Crystal Electrolyte with Fast Ion-Transport Channels for Solid Zinc-Ion Batteries

机译：A Novel Plastic-Crystal Electrolyte with Fast Ion-Transport Channels for Solid Zinc-Ion Batteries

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相关主题

摘要

Miniaturized solid zinc-ion batteries that are safe, environmentally friendly, and low-cost are ideal candidates for powering emerging microelectronics. However, sluggish Zn~(2+) mobility in solid phases hampers the viability of solid Zn~(2+) electrolytes and hence their practicability. Here, nanoscale Zn~(2+) channels are successfully engineered in a plastic-crystal electrolyte, thus activating fast Zn~(2+) solid-state transport. The ion-dipole interaction exerted by water molecules orients amphiphilic anions in bilayers, further forming a layered architecture backed by long-range van der Waals attractive forces. In the interlayer, the heteroleptic coordination contributed by the water molecule and anion frees the Zn~(2+) from anionic traps, leading to a high Zn~(2+) conductivity of 2.2 × 10~(?3) S cm~(?1). This elaborately tailored texture confers a combination of robust mechanical characteristics and outstanding electrochemical performance upon the resultant electrolyte. The applicability is demonstrated by the high Zn~(2+) platting/stripping efficiency (99.6%), durable longevity of symmetric Zn-Zn and Zn-MnO_2 cells, as well as the engineering of versatile micro batteries (MBs). This work provides new perspectives for developing super multivalent ion conductors through the innovative design of ion-conducting nanochannels.

著录项

获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号