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Stabilization, Characterization, and Electrochemical Applications of High-Entropy Oxides: Critical Assessment of Crystal Phase–Properties Relationship

机译:Stabilization, Characterization, and Electrochemical Applications of High-Entropy Oxides: Critical Assessment of Crystal Phase–Properties Relationship

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摘要

High-entropy oxides (HEOs), a class of newly emerging energy conversionand storage technology materials, have gained significant interest dueto their unique structure, complex stoichiometry, and correspondingsynergetic effect. Despite the increasing number of reported studiesrelated to HEOs in recent years, details of their structural propertiesand electrochemical activities are still lacking. Herein, the excitingdevelopments of HEOs regarding their design, synthesis, characterization,theoretical calculations, and electrochemical performances are outlined.The fundamentals of HEOs, including their strict definition, mainfeatures, and four-core aspect effects are presented. The differentsynthetic methods of HEOs are categorized to highlight the significanceof parameter optimization to ensure the single-phase stability of HEOs.The advances in characterization techniques on the local lattice andatomic distribution and the basic principles of combinatorial screeningmethods based on computational techniques are also elaborated. RecentHEO-based electrode/electrocatalysts toward Li-ion batteries and oxygencatalysis are reviewed to assess the potential applications of HEOs. Thisreview draws attention to the critical challenges of HEOs that are worthmore extensive explorations in the future.

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