Enhancing the Kinetics of Zinc Ion Deposition by Catalytic Ion in Polymer Electrolytes for Advanced Zn–MnO_2 Batteries

Jinling Hu; Yuanduo Qu; Fengwei ShiJunkai WangXia HeSiqi LiaoLianfeng Duan

首页> 外文期刊>Advanced functional materials >Enhancing the Kinetics of Zinc Ion Deposition by Catalytic Ion in Polymer Electrolytes for Advanced Zn–MnO_2 Batteries

【24h】

Enhancing the Kinetics of Zinc Ion Deposition by Catalytic Ion in Polymer Electrolytes for Advanced Zn–MnO_2 Batteries

机译：Enhancing the Kinetics of Zinc Ion Deposition by Catalytic Ion in Polymer Electrolytes for Advanced Zn–MnO_2 Batteries

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相关主题

摘要

The practicality of zinc-ion batteries (ZIBs) is compromise seriously becauseof the mutual restrictions of hydrogen evolution, by-product formation andzincdendrite growth. Herein, anhydrous gel polymer electrolytes (GPEs)with catalytic ions and in situdomain-constrained zinc ions are designed.Innovatively, copper ions are confined in the network structure of the gel foraccelerating the deposition and migration kinetics of zinc ions. Not only doesthis anhydrous GPEs exhibit strong mechanicaland thermal properties, butit also presents a high ionic conductivity (24.32 mS cm~（?1）) and a high zinc iontransference number (0.42). Consequently, the anhydrous GPEs is capable ofstable cycling of symmetrical Zn cells at 1 mA cm~（?2） with acumulative capacityof 1000 mAh cm~（?2） and maintaines a high discharge specific capacity of124.6 mAh g~（?1） after 1000 long-term cycles of the Zn-MnO2 battery (ZMB) at1 C. The synergistic catalytic strategy of composite gel opens new opportunitiesfor a promising pathway to facilitate the large-scale application of ZIBswith hydrogel electrolytes.

著录项

来源
《Advanced functional materials》 |2022年第51期|2209463.1-2209463.11|共11页
作者
Jinling Hu; Yuanduo Qu; Fengwei ShiJunkai WangXia HeSiqi LiaoLianfeng Duan;
展开▼
作者单位

Department of Chemistry and Key Laboratory for Preparation andApplication of Ordered Structural Materials of Guangdong ProvinceShantou UniversityShantou 515063, P. R. China;

Advanced Institute of Materials Science and School ofChemical EngineeringChangchun University of TechnologyChangchun 130012, P. R. China;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类
关键词
anhydrous gel polymer electrolytes; catalyses; collaborative optimization; deposition kinetics; Zn–MnO_2 batteries;

Enhancing the Kinetics of Zinc Ion Deposition by Catalytic Ion in Polymer Electrolytes for Advanced Zn–MnO_2 Batteries

摘要

著录项

相关主题

期刊订阅