Highly Efficient Oxidation of Propane at Low Temperature over a Pt-Based Catalyst by Optimization Support

Zhenpeng Huang; Jiajia Ding; Xinwei Yang

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Highly Efficient Oxidation of Propane at Low Temperature over a Pt-Based Catalyst by Optimization Support

机译：Highly Efficient Oxidation of Propane at Low Temperature over a Pt-Based Catalyst by Optimization Support

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Pt-based catalysts have attracted widespread attention in environmental protection applications,especially in the catalytic destruction of light alkane pollutants.However,developing a satisfying platinum catalyst with high activity,excellent water-resistance,and practical suitability for hydrocarbon combustion at low temperature is challenging.In this study,the Pt catalyst supported on the selected Nb2O5 oxide exhibited an efficient catalytic activity in propane oxidation and exceeded that of most catalysts reported in the literature.More importantly,the Pt/Nb2O5 catalyst maintained excellent activity and durability even after high-temperature aging at 700 ℃ and under harsh working conditions,such as a certain degree of moisture,high space velocity,and composite pollutants.The excellent performance of the Pt/Nb2O5 catalyst was attributed to the abundant metallic Pt species stabilized on the surface of Nb2O5,which prompted the C-H bond dissociation ability as the rate-determining step.Furthermore,propane was initially activated via oxidehydrogenation and followed the acrylate species path as a more efficient propane oxidation path on the Pt/Nb2O5 surface.Overall,Pt/Nb2O5 can be considered a promising catalyst for the catalytic oxidation of alkanes from industrial sources and could provide inspiration for designing superb catalysts for the oxidation of light alkanes.

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《Environmental Science & Technology: ES&T》 |2022年第23期|17278-17287|共10页
作者
Zhenpeng Huang; Jiajia Ding; Xinwei Yang;
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作者单位

Key Laboratory for Advanced Materials and Research Institute of Industrial Catalysis,School of Chemistry & Molecular Engineering East China University of Science and Technology,Shanghai 200237,P.R China;

Key Laboratory for Advanced Materials and Research Institute of Industrial Catalysis,School of Chemistry & Molecular Engineering East China University of Science and Technology,Shanghai 200237,P.R.China;

Hudong Heavy Machinery Co.,Ltd.,Shanghai 200129,P.R.China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种英语
中图分类环境科学、安全科学;
关键词
propane oxidation; support effect; Pt catalyst; C-H bond dissociation; oxidation mechanism;

Highly Efficient Oxidation of Propane at Low Temperature over a Pt-Based Catalyst by Optimization Support

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