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首页> 外文期刊>Environmental Science & Technology: ES&T >Effect of Biomass Burning,Diwali Fireworks,and Polluted Fog Events on the Oxidative Potential of Fine Ambient Particulate Matter in Delhi,India
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Effect of Biomass Burning,Diwali Fireworks,and Polluted Fog Events on the Oxidative Potential of Fine Ambient Particulate Matter in Delhi,India

机译:Effect of Biomass Burning,Diwali Fireworks,and Polluted Fog Events on the Oxidative Potential of Fine Ambient Particulate Matter in Delhi,India

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摘要

We investigated the influence of biomass burning(BURN),Diwali fireworks,and fog events on the ambient fine particulate matter(PM_(2.5))oxidative potential(OP)during the postmonsoon(PMON)and winter season in Delhi,India.The real-time hourly averaged OP(based on a dithiothreitol assay)and PM_(2.5)chemical composition were measured intermittently from October 2019 to January 2020.The peak extrinsic OP(OPv:normalized by the volume of air)was observed during the winter fog(WFOG)(5.23 ± 4.6 nmol·min·m~(-3)),whereas the intrinsic OP(OPm; normalized by the PM_(2.5)mass)was the highest during the Diwali firework-influenced period(29.4 ± 18.48 pmol·min~(-1)·μg~(-1)).Source apportionment analysis using positive matrix factorization revealed that traffic + resuspended dust-related emissions(39%)and secondary sulfate + oxidized organic aerosols(38%)were driving the OPv during the PMON period,whereas BURN aerosols dominated(37%)the OPv during the WFOG period.Firework-related emissions became a significant contributor(~32%)to the OPv during the Diwali period(4 day period from October 26 to 29),and its contribution peaked(72%)on the night of Diwali.Discerning the influence of seasonal and episodic sources on health-relevant properties of PM_(2.5),such as OP,could help better understand the causal relationships between PM_(2.5)and health effects in India.

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