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Anisotropically Oriented Carbon Films with Dual-Function of Efficient Heat Dissipation and Excellent Electromagnetic Interference Shielding Performances

机译:Anisotropically Oriented Carbon Films with Dual-Function of Efficient Heat Dissipation and Excellent Electromagnetic Interference Shielding Performances

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摘要

The rapid development of next-generation portable electronic devices urgentlyrequires dual-functional materials that possess both efficient heat dissipationand outstanding electromagnetic interference (EMI) shielding performances.In this study, anisotropically oriented carbon films with high thermal conductivityand excellent EMI shielding properties are prepared through an innovativeglucose hydrogel-controllable carbonization method. The horizontalalignment of nanocrystalline graphite results in oriented structures with anextremely high in-plane thermal conductivity of 439.9 W m~(?1) K~(?1), exhibitinga more effective heat-dissipating capacity on smartphones than their commercialgraphite counterparts. Additionally, owing to multiple internal reflectionsarising from the oriented structures, the films exhibit an EMI shieldingeffectiveness (SE) of 21.72 dB at an ultrathin thickness of 480 nm in theX-band and an extraordinarily high absolute shielding effectiveness (SSE/t) of275 883 dB cm~2 g~(?1), significantly outperforming most of the reported syntheticmaterials. Furthermore, the flexibility, high mechanical strength, andstability of the films are demonstrated and therefore show promising applicationprospects. This study offers a facile yet feasible strategy for preparingdual-functional materials to address the heat emission and EMI problemsof advanced electronic devices in a more economical and environmentallyfriendly manner.

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