Liquid-dependent impedance induced by vapor condensation and percolation in nanoparticle film

Kano Shinya; Mekaru Harutaka

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Liquid-dependent impedance induced by vapor condensation and percolation in nanoparticle film

机译：Liquid-dependent impedance induced by vapor condensation and percolation in nanoparticle film

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摘要

A liquid-dependent impedance is observed by vapor condensation and percolation in the void space between nanoparticles. Under the Laplace pressure, vapor is effectively condensed into liquid to fill the nanoscale voids in an as-deposited nanoparticle film. Specifically, the transient impedance of the nanoparticle film in organic vapor is dependent on the vapor pressure and the conductivity of the condensed liquid. The response follows a power law that can be explained by the classical percolation theory. The condensed vapor gradually percolates into the void space among nanoparticles. A schematic is proposed to describe the vapor condensation and percolation dynamics among the nanoparticles. These findings offer insights into the behavior of vapor adsorbates in nanomaterial assemblies that contain void space.

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来源
《Nanotechnology》 |2022年第10期|共9页
作者
Kano Shinya; Mekaru Harutaka;
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作者单位

Natl Inst Adv Ind Sci & Technol;

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原文格式 PDF
正文语种英语
中图分类特种结构材料;
关键词
vapor; capillary condensation; nanoparticles; percolation theory; impedance; AC CONDUCTIVITY; THIN-FILMS; HUMIDITY; SENSORS; WATER;

Liquid-dependent impedance induced by vapor condensation and percolation in nanoparticle film

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