Monolith or Powder: Improper Sample Pretreatment May Mislead the Understanding of Industrial V2O5-WO3/TiO2 Catalysts Operated in Stationary Resources

Gongda Chen; Jianjun Chen; Xiaoping Chen

首页> 外文期刊>Environmental Science & Technology: ES&T >Monolith or Powder: Improper Sample Pretreatment May Mislead the Understanding of Industrial V2O5-WO3/TiO2 Catalysts Operated in Stationary Resources

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Monolith or Powder: Improper Sample Pretreatment May Mislead the Understanding of Industrial V2O5-WO3/TiO2 Catalysts Operated in Stationary Resources

机译：Monolith or Powder: Improper Sample Pretreatment May Mislead the Understanding of Industrial V2O5-WO3/TiO2 Catalysts Operated in Stationary Resources

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Although various characterizations are widely applied to commercial V2O5-WO3/TiO2 catalysts, the influence of the catalyst physical structure, i.e., monolith or powder, on the characterization results has not been investigated. Several important catalytic behaviors and phenomena were observed in this study using V2O5-WO3/TiO2 monolithic catalysts employed for over S000 h in various stationary flue gases, and many of the results were only observable on monolithic catalysts, such as depth-dependent distribution of external elements, penetration of As2O3, and the formation of Tl2O-TiO2 p-n junctions. If the monolith is ground into powder states, it will alter or destroy the catalyst surface and remove important clues closely related to catalytic performance under working conditions. The redox and acidity properties of V2O5-WO3/TiO2 obtained from powder samples may be significantly different from their true state under working conditions, resulting in a misperception of catalyst performance. Therefore, a cautious pretreatment should be taken into careful consideration when analyzing commercial honeycomb V2O5-WO3/ TiO2 catalysts.

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来源
《Environmental Science & Technology: ES&T》 |2022年第22期|16394-16399|共6页
作者
Gongda Chen; Jianjun Chen; Xiaoping Chen;
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作者单位

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing 100084, PR China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种英语
中图分类环境科学、安全科学;
关键词
commercial catalyst; selective catalytic reduction; characterization; pretreatment method; distortion;

Monolith or Powder: Improper Sample Pretreatment May Mislead the Understanding of Industrial V2O5-WO3/TiO2 Catalysts Operated in Stationary Resources

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