Scanning electrochemical microscopy methods (SECM) and ion-selective microelectrodes for corrosion studies

Traxler Ines; Singewald Tanja D.; Schimo-Aichhorn GabrielaHild SabineValtiner Markus

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Scanning electrochemical microscopy methods (SECM) and ion-selective microelectrodes for corrosion studies

机译：Scanning electrochemical microscopy methods (SECM) and ion-selective microelectrodes for corrosion studies

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摘要

Over the last 30 years, scanning electrochemical microscopy (SECM) has become a fundamental technique in corrosion research. With its high spatial resolution and its ability to study local electrochemistry, it contributes essentially to the understanding of corrosion processes. By using selective micro- and nano-sensors, concentration profiles of different corrosion relevant species, from protons to metal ions, can be established. This review provides a comprehensive overview about SECM based techniques and discusses various types of microsensors, including materials selection and preparation techniques, and it provides extensive tables on redox-couples for specific corrosion research applications.

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来源
《Corrosion Reviews》 |2022年第6期|515-542|共28页
作者
Traxler Ines; Singewald Tanja D.; Schimo-Aichhorn GabrielaHild SabineValtiner Markus;
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作者单位

CEST Ctr Electrochem & Surface Technol;

Johannes Kepler Univ Linz;

Vienna Univ Technol;

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原文格式 PDF
正文语种英语
中图分类金属腐蚀与保护、金属表面处理;
关键词
ion-selective electrode; localized corrosion; SECM; ultramicro electrode; ALTERNATING-CURRENT MEASUREMENTS; IMAGING CONCENTRATION PROFILES; ELECTRON-TRANSFER KINETICS; SELF-ASSEMBLED MONOLAYERS; IN-SITU CHARACTERIZATION; PITTING PRECURSOR SITES; REDOX COMPETITION MODE; TIP COLLECTION MODE; NATIVE-OXIDE FILM; LOCALIZED CORROSION;

Scanning electrochemical microscopy methods (SECM) and ion-selective microelectrodes for corrosion studies

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