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Switchable and Reversible p~+/n~+ Doping in 2D Semiconductors by Ionic 2D Minerals

机译:Switchable and Reversible p~+/n~+ Doping in 2D Semiconductors by Ionic 2D Minerals

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摘要

2D semiconductors are promising for fabricating miniaturized and flexibleelectronic devices. The manipulation of polarities in 2D semiconductors iskey to fabricate functional devices and circuits. However, the switchableand reversible control of polarity in 2D semiconductors is challenging dueto their ultrathin body. Herein, a reversible and non-destructive method isdeveloped to dope 2D semiconductors by using ionic 2D minerals as theelectrostatic gating. The 2D semiconductor channel can be reversibly transformedbetween n~+ and p~+ types with carrier concentrations of 1.59 × 10~(13) and6.82 × 10~(12) cm~(?2), respectively. With the ability to in situ control carrier typeand concentration in 2D semiconductors by ionic gating, a reversible PN/NP junction and programmable logic gate are demonstrated in such devices.This 2D mineral materials-based ionic doping approach provides an alternativemethod for achieving multi-functional and complex circuits in an all-2Dmaterial flatform.

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