• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>The Journal of Chemical Physics >The effect of explicit counterion binding on the transference number of polyelectrolyte solutions
【24h】

The effect of explicit counterion binding on the transference number of polyelectrolyte solutions

机译：The effect of explicit counterion binding on the transference number of polyelectrolyte solutions

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相关主题

摘要

Polyelectrolyte solutions have been proposed as a method to improve the efficiency of lithium-ion batteries by increasing the cation transference number because the polymer self-diffusion coefficient is much lower than that of the counterion. However, this is not necessarily true for the polymer mobility. In some cases, negative transference numbers have been reported, which implies that the lithium ions are transporting to the same electrode as the anion, behavior that is often attributed to a binding of counterions to the polyion. We use a simple model where we bind some counterions to the polymer via harmonic springs to investigate this phenomenon. We find that both the number of bound counterions and the strength of their binding alter the transference number, and, in some cases, the transference number is negative. We also investigate how the transference number depends on the Manning parameter, the ratio of the Bjerrum length to charge separation along the chain. By altering the Manning parameter, the transference number can almost be doubled, which suggests that charge spacing could be a way to increase the transference number of polyelectrolyte solutions. Published under an exclusive license by AIP Publishing.

著录项

获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号