Chemo- and regioselective oxidation of substituted 2,3,4,9-tetrahydro-1H-carbazoles

Mikhalyonok Sergei G.; Savelyev Alexander I; Kuzmenok Nina M.Bezborodov Vladimir S.

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Chemo- and regioselective oxidation of substituted 2,3,4,9-tetrahydro-1H-carbazoles

机译：Chemo- and regioselective oxidation of substituted 2,3,4,9-tetrahydro-1H-carbazoles

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Chemo- and regioselective oxidation of substituted 2,3,4,9-tetrahydro-1H-carbazoles was used to obtain 2,3,4,9-tetrahydro-1H-carbazol-1-ones or 3,4,5,6-tetrahydro-1H-1-benzazonine-2,7-diones depending on the nature of the selected oxidant. In the case of benzo-fused tetrahydrocarbazoles, the main direction of the process was complete aromatization of the polycyclic system. Besides the influence of the substrate type, we also explored the role of various oxidants, solvents, and the concentration of reactants in this oxidation process.

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《Chemistry of heterocyclic compounds》 |2022年第9期|403-411|共9页
作者
Mikhalyonok Sergei G.; Savelyev Alexander I; Kuzmenok Nina M.Bezborodov Vladimir S.;
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Belarusian State Technol Univ;

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正文语种英语
中图分类杂环化合物;
关键词
hypervalent iodine compounds; selenium dioxide; 3; 4; 5; 6-tetrahydro-1H-1-benzazonine-2; 7-diones; 2; 9-tetrahydro1H-carbazoles; 9-tetrahydro-1H-carbazol-1-ones; chemo- and regioselectivity; oxidation; Riley reaction; N BOND FORMATION; TETRAHYDROCARBAZOLES; DERIVATIVES; CARBAZOLES; ALKALOIDS; DISCOVERY; INDOLES; ROUTE;

Chemo- and regioselective oxidation of substituted 2,3,4,9-tetrahydro-1H-carbazoles

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