A Comparative Study on the Oxidation Mechanisms of Substituted Phenolic Pollutants by Ferrate(VI)through Experiments and Density Functional Theory Calculations

Nannan Wu; Mingzhu Liu; Bingru Tian

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A Comparative Study on the Oxidation Mechanisms of Substituted Phenolic Pollutants by Ferrate(VI)through Experiments and Density Functional Theory Calculations

机译：A Comparative Study on the Oxidation Mechanisms of Substituted Phenolic Pollutants by Ferrate(VI)through Experiments and Density Functional Theory Calculations

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In this work,the oxidation of five phenolic contaminants by ferrate(VI)was comparatively investigated to explore the possible reaction mechanisms by combined experimental results and theoretical calculations.The second-order rate constants were positively correlated with the energy of the highest occupied molecular orbital.Considering electronic effects of different substituents,the easy oxidation of phenols by ferrate(VI)could be ranked as the electron-donating group(-R)>weak electron-withdrawing group(-X)>strong electron-withdrawing group(-(C=O)-).The contributions of reactive species(Fe(VI),Fe(V)/(IV),and ·OH)were determined,and Fe(VI)was found to dominate the reaction process.Four main reaction mechanisms including single-oxygen transfer(SOT),double-oxygen transfer(DOT),·OH attack,and electron-transfer-mediated coupling reaction were proposed for the ferrate(VI)oxidation process.According to density functional theory calculation results,the presence of-(C=O)-was more conducive for the occurrence of DOT and ·OH attack reactions than-R and-X,while the tendency of SOT for different substituents was-R>-(C=O)->-X and that of e~--transfer reaction was-R>-X>-(C=O)-.Moreover,the DOT pathway was found in the oxidation of all four substituted phenols,indicating that it may be a common reaction mechanism during the ferrate(VI)oxidation of phenolic compounds.

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《Environmental Science & Technology: ES&T》 |2023年第29期|10629-10639|共11页
作者
Nannan Wu; Mingzhu Liu; Bingru Tian;
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作者单位

State Key Laboratory of Pollution Control and Resources Reuse,School of the Environment,Nanjing University,Nanjing 210023 Jiangsu,P.R.China;

State Key Laboratory of Pollution Control and Resources Reuse,School of the Environment,Nanjing University,Nanjing 210023 Jiangsu,P.R,China;

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收录信息美国《科学引文索引》(SCI);美国《工程索引》(EI);美国《生物学医学文摘》(MEDLINE);美国《化学文摘》(CA);
原文格式 PDF
正文语种英语
中图分类环境科学、安全科学;
关键词
ferrate(VI); phenolic contaminants; reactive species; reaction mechanisms; DFT calculations;

A Comparative Study on the Oxidation Mechanisms of Substituted Phenolic Pollutants by Ferrate(VI)through Experiments and Density Functional Theory Calculations

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