State-to-state cross sections and rate coefficients for transitions between rotational/fine-structure levels of OH(X-2 Pi) induced by collisions with atomic hydrogen are reported in this work. The scattering calculations take into account the full open-shell character of the OH + H system and include the four potential energy surfaces ((1)A ', (1)A '', (3)A ', (3)A '') that correlate with the OH(X-2 Pi) + H(S-2) asymptote. Three of these surfaces are repulsive, while the deep H2O well is present on one surface ((1)A '). The OH + H potential energy curves calculated by Alexander et al. [J. Chem. Phys. 121, 5221 (2004)] are employed in this work. Time independent quantum scattering calculations were performed using the quantum statistical method of Rackham and co-workers [Chem. Phys. Lett. 343, 356 (2001)] because of the presence of the deep H2O well. The computed cross sections include contributions from direct scattering, as well formation and decay of a transient collision complex since the transient HO-H complex is expected to decay nonreactively. Rate coefficients for OH-H inelastic collisions are of interest for astrophysical applications.
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