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Methylammonium and Bromide-Free Tin-Based Low Bandgap Perovskite Solar Cells

机译:Methylammonium and Bromide-Free Tin-Based Low Bandgap Perovskite Solar Cells

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摘要

Lead halide-based perovskite solar cells (PSCs) are intriguing candidatesfor photovoltaic technology because of their high efficiency, low cost, andsimple process advantages. Owing to lead toxicity, PSCs based on partially/fully substituted Pb with tin have attracted tremendous attention,which would enable the ideal bandgap to approach the Shockley-Queisser(S-Q) limit. Especially, methylammonium (MA), bromide-free, tin-basedperovskites are striking, because of the intrinsic poor stability of MA andblue shift caused by the incorporation of Br~?. The first section of this reviewemphasizes the motivation for studying single-junction MA, Br-free, andSn-based perovskites. The film quality improvement strategies of Sn-basedperovskites, including additive, composition, dimensional, and interfaceengineering toward high-efficiency devices are comprehensively overviewed.Moreover, strategies to improve stability, where shelf, thermal andoperational stabilities of the devices are summarized. Finally, this reviewconcludes with a discussion of actual limitations and future prospects forSn-based PSCs.

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