Super Long-Cycling All-Solid-State Battery with Thin Li_6PS_5Cl-Based Electrolyte

Sijie Liu; Le Zhou; Jian HanKaihua WenShundong GuanChuanjiao XueZheng ZhangBen XuYuanhua LinYang ShenLiangliang LiCe-Wen Nan

首页> 外文期刊>Advanced energy materials >Super Long-Cycling All-Solid-State Battery with Thin Li_6PS_5Cl-Based Electrolyte

【24h】

Super Long-Cycling All-Solid-State Battery with Thin Li_6PS_5Cl-Based Electrolyte

机译：Super Long-Cycling All-Solid-State Battery with Thin Li_6PS_5Cl-Based Electrolyte

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相关主题

摘要

All-solid-state batteries (ASSBs) using sulfide electrolytes have attracted everincreasinginterest due to high ionic conductivity of the sulfides. Nevertheless,a thin, strong solid-state sulfide electrolyte membrane maintaining highionic conductivity is highly desired for ASSBs. Here, a thin, flexible compositesolid electrolyte membrane composed of argyrodite sulfide Li6PS5Cl and apolar poly(vinylidene fluoride-co-trifluoroethylene) (P(VDF-TrFE)) framework isprepared via an electrospinning-infiltration-hot-pressing method. The interactionbetween Li_6PS_5Cl and polar P(VDF-TrFE) ensures a high lithium-ion conductivity(≈1.2 mS cm–1) at room temperature and good mechanical ductilityof the composite electrolyte membrane. The coin-type ASSB cells with thethin composite electrolyte membrane, a composite cathode of LiNbO3-coatedLiNi_(0.8)Co_(0.1)Mn_(0.1）O_2 and Li6PS5Cl, and a lithium-indium anode, show supercycling performance, and the capacity retention is 92% after 1000 cycles and71% even after 20 000 cycles at 1.0 mA cm~（–2） (i.e., 1.61 C) at room temperature.Moreover, pouch-type ASSB cells with a high mass loading of active materialsare made to demonstrate the potential and feasibility in future commercialapplications.

著录项

来源
《Advanced energy materials》 |2022年第25期|2200660.1-2200660.9|共9页
作者
Sijie Liu; Le Zhou; Jian HanKaihua WenShundong GuanChuanjiao XueZheng ZhangBen XuYuanhua LinYang ShenLiangliang LiCe-Wen Nan;
展开▼
作者单位

State Key Laboratory of New Ceramics and Fine ProcessingSchool of Materials Science and EngineeringTsinghua UniversityBeijing 100084, China;

Beijing Computational Science Research CenterBeijing 100084, China;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类
关键词
ASSLBs; composite solid electrolytes; Li_6PS_5Cl; P(VDF-TrFE); sulfideelectrolytes;

Super Long-Cycling All-Solid-State Battery with Thin Li_6PS_5Cl-Based Electrolyte

摘要

著录项

相关主题

期刊订阅