Aggregation-induced emission-active poly (β-lactam) prepared by Staudinger polymerization as specific probe to Fe~(3+) ions and its antimicrobial properties

Xue Meng; Da Zhang; Meng WangRonghui ZhaoPengfei ZhangJingyuan ZhaoKuilin Deng

首页> 外文期刊>Polymers for advanced technologies >Aggregation-induced emission-active poly (β-lactam) prepared by Staudinger polymerization as specific probe to Fe~(3+) ions and its antimicrobial properties

【24h】

Aggregation-induced emission-active poly (β-lactam) prepared by Staudinger polymerization as specific probe to Fe~(3+) ions and its antimicrobial properties

机译：Aggregation-induced emission-active poly (β-lactam) prepared by Staudinger polymerization as specific probe to Fe~(3+) ions and its antimicrobial properties

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相关主题

摘要

For the nontraditional aggregation-induced emission (AIE) active polymers, the heterocyclic structure on the macromolecular backbone and side chains play a crucial role in its fluorescence generation. In this paper, we facilely prepared a series of poly (β-lactam) derivatives (PLTM) by Staudinger polymerization. As expected, PLTMs with four-membered heterocycles along the main-chain shows a remarkable AIE performance with the fluorescence emission at 520 nm, while no fluorescence was observed for both β-lactam (repeating unit) and a model polymer for PLTM. The fluorescence properties of PLTMs greatly depend on the intramolecular aggregation of β-lactam structures, the size of the substituents, and appropriate length of CH_2 spacer. In addition, PLTMs can specifically detect Fe~(3+) ions with a limit of detection (LOD) of 7.2 μM even in the presence of other 13 metal ions. Similar to the biological activity of β-lactam, AIE-active PLTMs shows a bactericidal effect on Staphylococcus aureus and Escherichia coli with the minimum inhibitory concentration of about 8 and 4 mg/mL. In brief, the preparation and versatility of PLTMs with β-lactam structure provide useful references for designing other nontraditional AIE-active polymers as well as for ion detection and antibacterial processes.

著录项

来源
《Polymers for advanced technologies》 |2022年第12期|4120-4130|共11页
作者
Xue Meng; Da Zhang; Meng WangRonghui ZhaoPengfei ZhangJingyuan ZhaoKuilin Deng;
展开▼
作者单位

College of Chemistry & Environmental Science, Hebei University;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类高分子化学（高聚物）;
关键词
Aggregation-induced emission; Facile synthesis; Poly(β-lactam); Staudinger polymerization;

Aggregation-induced emission-active poly (β-lactam) prepared by Staudinger polymerization as specific probe to Fe~(3+) ions and its antimicrobial properties

摘要

著录项

相关主题

期刊订阅