...
  • 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Proceedings of the National Academy of Sciences of the United States of America. >Photochemistry of oxidized Hg(I) and Hg(II) species suggests missing mercury oxidation in the troposphere
【24h】

Photochemistry of oxidized Hg(I) and Hg(II) species suggests missing mercury oxidation in the troposphere

机译：Photochemistry of oxidized Hg(I) and Hg(II) species suggests missing mercury oxidation in the troposphere

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相关主题

摘要

Mercury (Hg), a global contaminant, is emitted mainly in its elemental form Hg-0 to the atmosphere where it is oxidized to reactive Hg'' compounds, which efficiently deposit to surface ecosystems. Therefore, the chemical cycling between the elemental and oxidized Hg forms in the atmosphere determines the scale and geographical pattern of global Hg deposition. Recent advances in the photochemistry of gas-phase oxidized Hg' and Hg'' species postulate their photodissociation back to Hg-0 as a crucial step in the atmospheric Hg redox cycle. However, the significance of these photodissociation mechanisms on atmospheric Hg chemistry, lifetime, and surface deposition remains uncertain. Here we implement a comprehensive and quantitative mechanism of the photochemical and thermal atmospheric reactions between Hg-0, Hg', and Hg '' species in a global model and evaluate the results against atmospheric Hg observations. We find that the photochemistry of Hg' and Hg '' leads to insufficient Hg oxidation globally. The combined efficient photoreduction of Hg' and Hg '' to Hg-0 competes with thermal oxidation of Hg-0, resulting in a large model overestimation of 99% of measured Hg-0 and underestimation of 51% of oxidized Hg and similar to 66% of Hg '' wet deposition. This in turn leads to a significant increase in the calculated global atmospheric Hg lifetime of 20 mo, which is unrealistically longer than the 3-6 mo range based on observed atmospheric Hg variability. These results show that the Hg' and Hg '' photoreduction processes largely offset the efficiency of bromine-initiated Hg-0 oxidation and reveal missing Hg oxidation processes in the troposphere.

著录项

获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号