Crystal Structure of 1,2,3,4-Tetrahaptohexakiscarbomethoxybenzene (eta(5)-Pentamethylcyclopentadienyl) Rhodium Complex

Kollipara Mohan Rao; Lapasam Agreeda; Kaminsky Werner

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Crystal Structure of 1,2,3,4-Tetrahaptohexakiscarbomethoxybenzene (eta(5)-Pentamethylcyclopentadienyl) Rhodium Complex

机译：Crystal Structure of 1,2,3,4-Tetrahaptohexakiscarbomethoxybenzene (eta(5)-Pentamethylcyclopentadienyl) Rhodium Complex

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The title complex (1), C28H33O12Rh, has been isolated as a major product during the reaction of strained azido thiourea rhodium complex with dimethyl acetylene dicarboxylate. This compound is isolated as air-stable bright red crystals and crystallizes in the triclinic space group P1 over bar } with Z = 2. The Rh(I) atoms, lying on center, are coordinated by the four carbon atoms of the benzene ring. The Rh atom revealed an unusual heptahedral coordination sphere. It is one of the rare examples of compounds formed by cyclotrimerization of alkynes. The Cp* moiety is disordered over two sets of sites with occupancies of 50%.

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《Journal of chemical crystallography》 |2021年第2期|288-292|共5页
作者
Kollipara Mohan Rao; Lapasam Agreeda; Kaminsky Werner;
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作者单位

North Eastern Hill Univ, Ctr Adv Studies Chem, Shillong 793022, Meghalaya, India;

Univ Washington, Dept Chem, Seattle, WA 98195 USA;

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正文语种英语
中图分类晶体学;
关键词
Rhodium; Cyclotrimerization; Crystal structure;

Crystal Structure of 1,2,3,4-Tetrahaptohexakiscarbomethoxybenzene (eta(5)-Pentamethylcyclopentadienyl) Rhodium Complex

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