This paper details the diassociative analogue of results concerning the Schur multiplier and other extension-theoretic concepts that originate in group theory. We first prove that covers of diassociative algebras are unique. Second, we show that the multiplier of a diassociative algebra is characterized by the second cohomology group with coefficients in the field. Third, we establish criteria for when the center of a cover maps onto the center of the algebra. Along the way, we obtain a collection of exact sequences, characterizations, and a brief theory of unicentral diassociative algebras and stem extensions. This paper is part of an ongoing project to advance extension theory in the context of several Loday algebras.
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