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首页> 外文期刊>Journal of Applied Polymer Science >Synthesis and performance of a novel polycarboxylate superplasticizer through grafting the β‐cyclodextrin on the side chain by click reaction
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Synthesis and performance of a novel polycarboxylate superplasticizer through grafting the β‐cyclodextrin on the side chain by click reaction

机译：Synthesis and performance of a novel polycarboxylate superplasticizer through grafting the β‐cyclodextrin on the side chain by click reaction

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Abstract A novel monovinyl β‐cyclodextrin monomer (β‐P) is employed to synthesize polycarboxylate superplasticizers with β‐cyclodextrin (β‐CD) grafted on the end of side chain PAA‐g‐(β‐P)nHPEG, n is the mass ratio of β‐P in macromonomer, n = 3 ~ 9. β‐P is synthesized through grafting β‐CD on the polyoxyethylene (PEO) via click reaction, which is the first try to superimpose the steric hindrance effect of PEO and β‐CD during the preparation of polycarboxylate superplasticizer. FTIR, 1H NMR, GPC, and DLS are used to characterize the molecular structure of the intermediates and the products. Compared with PAA‐g‐HPEG (PCE0) only with PEO as side chains, cement paste containing PAA‐g‐(β‐P)7HPEG has the largest fluidity; PAA‐g‐(β‐P)9HPEG corresponds to the best fluidity retention performance; cement paste containing PAA‐g‐(β‐P)nHPEG has shorter setting time. The DLS results reveal that the introduction of β‐CD in PAA‐g‐(β‐P)nHPEG extends the side chain length and increases the steric hindrance effect. The adsorption test results show that the novel PCE has good slump retention performance because it is adsorbed on cement particles less but more lives in the liquid phase with the n increasing. This study provides a new approach to synthesize high‐performance polycarboxylate superplasticizer.

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