Catalytic pyrolysis and kinetic study of real-world waste plastics: multi-layered and mixed resin types of plastics

Irma Kremer; TihomirTomi?; Zvonimir Katan?i?Matko ErcegSasa PapugaJelena ParlovVukovi?Daniel Rolph Schneider

首页> 外文期刊>Clean technologies and environmental policy >Catalytic pyrolysis and kinetic study of real-world waste plastics: multi-layered and mixed resin types of plastics

【24h】

Catalytic pyrolysis and kinetic study of real-world waste plastics: multi-layered and mixed resin types of plastics

机译：Catalytic pyrolysis and kinetic study of real-world waste plastics: multi-layered and mixed resin types of plastics

获取原文

获取原文并翻译 | 示例

掌桥外文数据库（机构版） >>

开具论文收录证明 >>

文献代查 >>

页面导航

摘要
著录项
相关主题

摘要

Multi-layered and mixed resin types of plastics are a great challenge for the waste recycling industry. The majority consist of two or more types of polymers, making it difficult to recycle mechanically, which leads to landfill or incineration plant. As a way of thermochemical recycling, pyrolysis is a promising cleaner technology that could use this plastics waste stream potential and convert it into valuable products like fuels. The hypotheses of this research are that the average apparent activation energy of multi-layered and mixed resin plastic real-world waste samples can be decreased with the addition of selected iron-modified zeolite catalyst and that catalytic pyrolysis in fixed bed reactor will give products that show good potential for use as an energy vector. To evaluate activation energy, kinetic analysis was conducted using the isoconversional model-free Friedman model in conjunction with the multivariate nonlinear regression method. Pyrolysis products were analysed using nuclear magnetic resonance spectroscopy, Fourier transform infrared spectroscopy and calorimetry. The catalyst significantly reduced the activation energy of the flexible plastic film sample, which means that the process with catalyst requires less energy consumption. In the case of rigid plastics, the activation energy was lower at the beginning of the process with the catalyst. The catalyst reduced pyrolytic condensates' viscosity of both samples. Analyses revealed how catalyst promoted the formation of aliphatic compounds in flexible plastics film oil, monoaromatic compounds in rigid plastics oil, and a significant decrease in polyaromatic compounds that degrade the quality of the fuel. The values of higher heating value were high (36-42 MJ/kg). Finally, the pyrolytic oil composition revealed satisfying quality and good potential for further use as an energy vector due to the high higher heating value.

著录项

来源
《Clean technologies and environmental policy》 |2022年第2期|677-693|共17页
作者
Irma Kremer; TihomirTomi?; Zvonimir Katan?i?Matko ErcegSasa PapugaJelena ParlovVukovi?Daniel Rolph Schneider;
展开▼
作者单位

Faculty of Mechanical Engineering and Naval Architecture, University of Zagreb, Zagreb, Croatia;

Faculty of Chemical Engineering and Technology, University of Zagreb, Zagreb, Croatia;

Faculty of Chemistry and Technology, University of Split, Split, CroatiaFaculty of Technology, University of Banja Luka, Banja Luka, Bosnia and HerzegovinaINA-Industrija nafte d.d., Zagreb, Croatia;

展开▼
收录信息
原文格式 PDF
正文语种英语
中图分类
关键词
Multi-layered plastics; Mixed resin plastics; Thermochemical recycling; Pyrolysis; Dynamic thermogravimetric analysis; Kinetic study; Zeolite catalyst;

Catalytic pyrolysis and kinetic study of real-world waste plastics: multi-layered and mixed resin types of plastics

摘要

著录项

相关主题

期刊订阅