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An oxidant-free and mild approach to fluorenones via direct excitation of aldehyde

机译:An oxidant-free and mild approach to fluorenones via direct excitation of aldehyde

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In a recent issue of Angewandte Chemie International Edition, Wu and co-workers reported a novel C(sp~2)-H bond-activation approach to synthesizing fluorenones, xanthones, and thioxan-thones. It features cobaloxime as the redox catalyst to stabilize the active triplet-state intermediate and eliminate the β-H under mild conditions through a single-electron-transfer pathway.

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