Recently in Nature Communications, Wan and co-workers introduced a surface-adsorption-induced radical-relay concept into heterogeneous Pd-catalyzed cross-coupling of quinolines and alcohols, which is totally different from homogeneous catalysts involving cy-clopalladated intermediates. The electron-deficient Pd nanopar-ticles demonstrated excellent catalytic performance and negligible Pd leaching after seven cycles.
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State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China;