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首页> 外文期刊>Proceedings of the National Academy of Sciences of the United States of America. >High-performance K-ion half/full batteries with superb rate capability and cycle stability
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High-performance K-ion half/full batteries with superb rate capability and cycle stability

机译:High-performance K-ion half/full batteries with superb rate capability and cycle stability

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摘要

Currently, a big problem for exploring K-ion half/full batteries is how to bring them with both high specific capacity and long cycling stability simultaneously, in terms of their intrinsically sluggish kinetics of K+ with larger radius than that of Li+, which often causes huge volume change over the electrochemical reaction. Herein, we report the exploration of high-performance K-ion half/full batteries with superb rate capability and cycle stability based on B-doped porous carbons with increased active sites and improved conductivity. The as-assembled K-ion half cell exhibits an excellent rate capability of 428 mA h g~ at 100 mA g~ and a high reversible specific capacity of 330 mA h g"1 with 120 specific capacity retention after 2,000 cycles at 2,000 mA g , which is state of the art among those based on carbon materials. Moreover, the as-constructed full cell delivers 98 specific capacity retention over 750 cycles at 500 mA g , which is superior to most of the analogs based on carbon materials that have been reported thus far, underscoring their potential applications in advanced energy storage.

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