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首页> 外文期刊>Polymers for advanced technologies >A holistic evaluation of the influence of shear rates and matrix viscosity on the properties of polypropylene/multi-walled carbon nanotubes composites
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A holistic evaluation of the influence of shear rates and matrix viscosity on the properties of polypropylene/multi-walled carbon nanotubes composites

机译：A holistic evaluation of the influence of shear rates and matrix viscosity on the properties of polypropylene/multi-walled carbon nanotubes composites

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摘要

In this work, a comparative study on the electrical, morphological, and thermal properties of polypropylene/multiwalled carbon nanotubes (PP/CNT) composites which were prepared by three different processing methods, such as compression molding (CM, shear rate: ～0 s~(-1)), conventional injection molding (CIM, shear rate: ～10~2 s~(-1)), and microinjection molding (μIM, shear rate: ～10~5 s~(-1)), was reported. The difference in shear rates among these processing methods and matrix viscosity would significantly affect the state of filler distribution, thereby determining the properties of subsequent moldings. Electrical conductivity results showed that the percolation threshold of PP/CNT moldings followed a trend of μIM > CIM > CM. A higher degree of CNT orientation and a better filler distribution were achieved under the influence of higher shearing conditions, as corroborated by scanning electron microscope observations and Raman spectral analysis. Moreover, increasing filler concentrations played a positive role in improving the thermal stability of PP/CNT composites and the formation of CNT network was believed to be a contributing factor.

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