• 主题
高级搜索  >
历史搜索 清空历史
首页> 外文期刊>Advanced functional materials >In Situ Reconstruction of Partially Hydroxylated Porous Rh Metallene for Ethylene Glycol-Assisted Seawater Splitting
【24h】

In Situ Reconstruction of Partially Hydroxylated Porous Rh Metallene for Ethylene Glycol-Assisted Seawater Splitting

机译：In Situ Reconstruction of Partially Hydroxylated Porous Rh Metallene for Ethylene Glycol-Assisted Seawater Splitting

获取原文
获取原文并翻译 | 示例
           
页面导航
  • 摘要
  • 著录项
  • 相关主题

摘要

Designing efficient and durable electrocatalysts for seawater electrolysisshows a great research prospect, but it remains a significant challenge.Herein, we report the partially hydroxylated Rh metallene (Rh/RhOOH metallene)with porous, ultrathin, defect-rich and hetero-phase structure for ethyleneglycol (EG)-assisted seawater electrolysis. In parallel, the unique redoxeffect of RhOOH species and EG as well as the electroreduction effect riggersthe in situ reconstruction for the catalyst during electrocatalysis, which furtherproduces active Rh species to optimize the catalytic activity center andsurface catalytic reaction. Benefiting from the unique metallene structure andthe Rh/RhOOH heterogeneous structure, the Rh/RhOOH metallene exhibitssuperior electrocatalytic performance towards hydrogen evolution reaction(HER, overpotential of 29 mV) and EG oxidation reaction (EGOR, specificactivity of 1.051 mA cm~(–2)). Encouragingly, in the constructed EG-assistedseawater electrolysis system, the Rh/RhOOH metallene only needs a lowcell voltage of 0.678 V to achieve a current density of 10 mA cm~(–2) for energysavingH_2 production, which significantly reduces energy consumption comparedto conventional seawater electrolysis.

著录项

获取原文

客服邮箱：kefu@zhangqiaokeyan.com

京公网安备：11010802029741号 ICP备案号：京ICP备15016152号-6 六维联合信息科技 (北京) 有限公司©版权所有

  • 客服微信

  • 服务号