Hydrolytic Stability of Hydroxyphenyl Boronic Acids(HPBAs) and Employment of Poly(HPBAs) for Voltammetric Determination of Fluoride Levels in Dental Formulations and Beverages; Significance of Raw DPV Data for Chemometric Discrimination

Fatma Gulay Der; Gorkem Yalcin; Ece Ozcan BulbulHakan IleriBetul CihanMiray GokcanYekta Can EsitmezEmrah Kilinc

首页> 外文期刊>Electroanalysis >Hydrolytic Stability of Hydroxyphenyl Boronic Acids(HPBAs) and Employment of Poly(HPBAs) for Voltammetric Determination of Fluoride Levels in Dental Formulations and Beverages; Significance of Raw DPV Data for Chemometric Discrimination

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Hydrolytic Stability of Hydroxyphenyl Boronic Acids(HPBAs) and Employment of Poly(HPBAs) for Voltammetric Determination of Fluoride Levels in Dental Formulations and Beverages; Significance of Raw DPV Data for Chemometric Discrimination

机译：Hydrolytic Stability of Hydroxyphenyl Boronic Acids(HPBAs) and Employment of Poly(HPBAs) for Voltammetric Determination of Fluoride Levels in Dental Formulations and Beverages; Significance of Raw DPV Data for Chemometric Discrimination

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Abstract Physicochemical and electrochemical properties of hydroxyphenyl boronic acids(HPBAs) and their use in fluoride determinations were investigated. HPBAs were electropolymerized at pH 1.0–11.0 in 40–60 (v/v) methanol‐buffer. Differential pulse voltammetry(DPV) determinations of fluoride (with 1.0×10−5–1.0×10−4 M linearity based on potential shift) using poly(HPBAs) glassy carbon electrodes(GCEs) have −45.49 to +34.40 error range. Significance of raw DPV data for chemometric discrimination was investigated by principle component analysis. This is the first demonstration of fluoride determination with poly(HPBAs)GCEs and chemometric discrimination of pharmaceutical formulations so far. Due to the lack of experimental data in literature, current findings will make a contribution to literature.

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《Electroanalysis》 |2022年第11期|1711-1724|共14页
作者
Fatma Gulay Der; Gorkem Yalcin; Ece Ozcan BulbulHakan IleriBetul CihanMiray GokcanYekta Can EsitmezEmrah Kilinc;
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作者单位

University of Ege Faculty of Pharmacy Department of Analytical Chemistry;

Isparta University of Applied Sciences;

Istinye University IstanbulGensenta Pharmaceuticals Governmental Affairs Department;

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正文语种英语
中图分类电化学、电解、磁化学;
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Hydroxyphenyl boronic acids; boroxines; TGA; DPV; chemoinformatics;

Hydrolytic Stability of Hydroxyphenyl Boronic Acids(HPBAs) and Employment of Poly(HPBAs) for Voltammetric Determination of Fluoride Levels in Dental Formulations and Beverages; Significance of Raw DPV Data for Chemometric Discrimination

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