Reactions of Os-3(CO)(10)(mu-H)(2) and Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H) with pymS-SnPh3(pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

Joy Md Tuhinur R.; Ghosh Shishir; Kabir Shariff E.

首页> 外文期刊>Journal of chemical crystallography >Reactions of Os-3(CO)(10)(mu-H)(2) and Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H) with pymS-SnPh3(pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

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Reactions of Os-3(CO)(10)(mu-H)(2) and Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H) with pymS-SnPh3(pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

机译：Reactions of Os-3(CO)(10)(mu-H)(2) and Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H) with pymS-SnPh3(pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

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Reactivity of pymS-SnPh3(pymS = pyrimidine-2-thiolate) towards two unsaturated triosmium clusters Os-3(CO)(10)(mu-H)(2) and Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H) are investigated. Reaction of pymS-SnPh(3)with Os-3(CO)(10)(mu-H)(2) affords Os-3(CO)(10)(mu-pymS)(mu-H) (1) and Os-3(CO)(9)(mu(3)-pymS)(mu-H) (2), while with Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H) leads to the isolation of only Os-3(CO)(8)(mu-pymS)(mu-H)(mu-dppm) (3). In both reactions, the products are formed via incorporation of the thiolate part (pymS) of pymS-SnPh(3)into the parent clusters through Sn-S bond cleavage. Clusters1-3have been characterized by a combination of analytical and spectroscopic data together with single crystal X-ray diffraction analysis. Graphic Reactions of pymS-SnPh(3)with two unsaturated triosmium clusters have been investigated which resulted in the isolation and characterization of three triosmium clusters containing a pymS ligand.

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来源
《Journal of chemical crystallography》 |2021年第2期|257-264|共8页
作者
Joy Md Tuhinur R.; Ghosh Shishir; Kabir Shariff E.;
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作者单位

Jahangirnagar Univ, Dept Chem, Dhaka 1342, Bangladesh;

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正文语种英语
中图分类晶体学;
关键词
Osmium; Carbonyls; Pyrimidine-2-thiolate; Tin-sulfur bond cleavage; Crystal structure;

Reactions of Os-3(CO)(10)(mu-H)(2) and Os-3(CO)(8){mu(3)-Ph2PCH2P(Ph)C6H4}(mu-H) with pymS-SnPh3(pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand

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