Sum frequency generation (SFG) spectroscopy is a unique and powerful tool for investigating surfaces and interfaces at the molecular level. Phase-sensitive SFG (PS-SFG) is an upgraded technique that can overcome the inherent drawbacks of conventional SFG. Here we review several methods of PS-SFG developed and reported in 1990-2022. We introduce how and by which group each PS-SFG method was designed and built in terms of interferometer implementation for optical heterodyne detection, with one exception of a recent numerical method that does not rely on interferometry. We also discuss how PSSFG solved some typical problems on aqueous interfaces that were once left open by conventional SFG. These problems and their solutions are good examples to demonstrate why PS-SFG is essential.
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